No, you cannot be sure.
'Acceleration' is any change in the speed or direction of motion. If the car is driving around a curve and the speedometer indicates a constant speed, it's still accelerating, because its direction is constantly changing as long as it's on the curve.
A constant speed on the speedometer does not imply that the car is not accelerating. Acceleration occurs with changes in either speed or direction. For instance, turning a corner at a constant speed still results in acceleration due to the change in direction.
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